| Abstract | Manganese–nickel ferrites powder with general formula MnxNi1_xFe2O4 (x = 0.0, 0.2, 0.4) were synthesized through oxalate precursor route and sintered at 1000 _C. The X-ray diffraction (XRD) patterns were measured for the prepared samples to confirm the existence of single-phase structure. The crystallite size was estimated and found to be within the range 125–170 nm. To study the radiation effect on the structure and magnetic properties, a representative group of the investigated samples were irradiated by crays of 60Co source with a dose of 310 kGy. The XRD spectra were performed for the irradiated samples and compared with that of the pristine samples to estimate changes in the structure. The obtained results showed that the crystallite size increased by a factor of 10–16% after gamma irradiation. The lattice parameter also was increased due to the conversion of Fe3+ (0.64 إ) to Fe2+ (0.76 إ). The formula of the cation distribution of the ferrites samples was suggested at x = 0, 0.2, 0.4 before and after irradiation. The theoretical lattice parameter, sample density and porosity were calculated and compared with that obtained from the experimental data. Good agreement was found between theoretical and experimental structural data which confirms the proposed formula of cations distribution. The hysteresis curves were measured using vibrating sample magnetometer (VSM) for the unirradiated and irradiated samples and the saturation magnetization was estimated. The obtained results showed increase in saturation magnetizations (Ms) for all the samples by irradiation due to redistribution of the cations between A and B sites and changing the net magnetic moments. Theoretical calculation of magnetic moments and saturation magnetization using the proposed cations distribution of A and B sites confirmed the experimental results. The positron annihilation lifetime spectroscopy (PALS) was used to investigate the defects and changes in electron density after irradiation. The PAL parameters (s1, I1, s2, I2 and mean lifetime) show that the irradiation affects the size and concentration of the vacant type defects. The results reveal that there are some large voids (with radius ranged from 0.28 to 0.38 nm and mean value of 0.34 ± 0.04 nm in the studied samples). The obtained results indicate the high sensitivity of PALS technique to the enhanced structure changes due to gamma rays irradiation. |